[(2-Pyridyl)methanol-κ2 N,O]bis(thiocyanato-κN)manganese(II)
نویسندگان
چکیده
In the title complex, [Mn(NCS)(2)(C(6)H(7)NO)(2)], the Mn(II) atom shows site symmetry 2. The distorted octa-hedral environment of Mn(II) is defined by two N atoms [Mn-N = 2.217 (4) and 2.132 (5) Å] and one O atom [Mn-O 2.305 (4) Å]. There are inter-molecular O-H⋯S hydrogen bonds and inter-molecular π-π stacking inter-actions between adjacent (2-pyrid-yl)methano-late ligands [centroid-centroid distance = 3.5569 (7) Å], leading to a chain structure running along [100].
منابع مشابه
Di-μ-thiocyanato-κ2 N:S;κ2 S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3 N,N′,N′′}(thiocyanato-κN)cadmium)
In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thio-cyanate N:S-bridging ligands around an inversion center. One terminal thio-cyanate N atom and one N,N',N''-tridentate Schiff base ligand complete a distorted CdN(5)S octa-hedral geometry about each Cd(II) atom. In the crystal, the Schiff base aromatic rings of adjacent mol-ecules are arr...
متن کامل{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
The mol-ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio-cyanate ligands, forming a distorted octa-hedral geometry.
متن کاملCrystal structure of bis[4-(dimethylamino)pyridine-κN 1]bis(methanol-κO)bis(thiocyanato-κN)manganese(II)
The whole mol-ecule of the title compound, [Mn(NCS)2(CH3OH)2(C5H6N2)2], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di-methyl-amino)-pyridine ligands, two methanol ligands and two terminally N-bonded thio-cyanate anions, forming a slightly distorted octa-hedron. In the crystal, mol-ecules are linked by O-H⋯S hydrogen bond...
متن کاملcatena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2 N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2 N:S]
In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N'-bidentate Schiff base and four thio-cyanate ligands in a distorted octa-hedral N(5)S geometry. Bridging thio-cyanate ligands inter-connect adjacent [Mn(NCS)(2)(C(10)H(16)N(3))] units, giving rise to helical chains extending along the b axis. The chains are further linked...
متن کاملBis[(1-methyl-1H-benzimidazol-2-yl)methanol-κ2 N 3,O]bis(thiocyanato-κN)cobalt(II) methanol solvate
In the mononuclear title complex, [Co(NCS)(2)(C(9)H(10)N(2)O)(2)]·CH(3)OH, the cobalt(II) ion is surrounded by two (1-methyl-1H-benzimidazol-2-yl)methanol bidentate ligands and two thio-cyanate ligands, and exhibits a distorted octa-hedral coordination by four N atoms and two O atoms. The structure is consolidated by hydrogen bonds between the organic ligand, thio-cyanate anion and the uncoordi...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010